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Interpretation of laser desorption mass spectra of unexpected inorganic species found in a cosmetic sample of forensic interest: fingernail polish

NCJ Number
304173
Journal
Analytical and Bioanalytical Chemistry Volume: 394 Dated: 2009 Pages: 2029-2038
Date Published
2009
Length
10 pages
Annotation

Since laser desorption mass spectrometry (LDMS) has been used successfully to analyze colorants of forensic interest in a  variety of materials, the current article presents and interprets the most complex of such spectra obtained to date from a sample of fingernail polish.

 

Abstract

When analytes containing color are irradiated with a pulsed UV laser in the ion source of a mass spectrometer, molecules such as dyes or pigments absorb energy, resulting in their desorption and ionization. This method, laser desorption mass spectrometry (LDMS), has been used successfully to analyze colorants of forensic interest in a wide variety of materials. In the current study, Interpretation of the spectrum provided a unique opportunity to characterize the laser desorption mass spectra of some unexpected inorganic materials found in cosmetics, such as “broken glass”, cyanide compounds, and heavy metals. Also, the possibility of a useful forensic database of LDMS spectra of fingernail polishes was considered. (publisher abstract modified)

Date Published: January 1, 2009