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Isolation of strontium pools and isotope ratios in modern human hair

NCJ Number
Analytica Chimica Acta Dated: 2013
Brett J. Tipple; Thuan Chau; Lesley A. Chesson; Diego P. Fernandez; Jams R. Ehleringer
Date Published
0 pages

This study examined the effects of five hair-cleaning methodologies in determining the extent to which internal and external strontium signals can be isolated from human hair. 


The elements of human hair record specific information about an individual's health, diet, and surrounding environment. Strontium isotope ratios of human hair have attracted interest, since they potentially record an individual's environment. Yet, separating the external environmental signals from the internal dietary indicators has remained a challenge. Viewed by the authors as the first study of its kind, the current study used an in-line strontium purification methodology and a multi-collector inductively coupled plasma mass spectrometer to obtain high-precision strontium isotope ratio of human hair and of leachates of the different washing treatments. The study found that the different applications of an individual treatment removed a consistent amount of strontium from hair and that replicate analyses showed each treatment altered the strontium isotope ratios of hair consistently. A mass-balance approach was applied to demonstrate that strontium was quantitatively removed and was accounted for in either the treated hair or the leachate. The researchers observed that strontium isotope ratio varied as a function of treatment aggressiveness, suggesting that there was a fine-scale structuring of strontium within hair (transverse cross-sectional variations); these variations existed as differences in strontium concentrations and isotope ratios. As a result, the Sr isotope ratio of hair and hair leachates treated with the most aggressive cleaning methods reflected the isotope ratios of the interior and total exterior strontium signatures, respectively. The results of this study indicate that external environmental strontium signals can be distinguished from the internal signals and therefore permit the application of strontium isotope ratios of modern human hair for geospatial applications. (publisher abstract modified)